A good way to go about it is to ask around in your local region to see who's had good experience with a smog shop. Some of the shops are better than others, and if a shop has just been hit with a fine for passing someone, you obviously want to stay away from that one. Also, if they've never seen a Viper before, they can just as likely go over it with a fine-tooth comb because it's unfamiliar to them as be overwhelmed and miss things. These cars are hard to get past the visual...
I posted a while back about a shop I went to where the guy went over my GTS with a fine tooth comb, and almost sent me to a referee station because he couldn't see the cats on my car. Duh. The cats are covered by the side sills... He told me that if he sees something suspicious, and can't verify it is OK, he is obligated to put my VIN into the computer and flag my car. I flipped out and wanted to choke the guy... One thing you don't want is to have your car flagged and sent to a referee. Once your VIN is in their system, it will haunt you until you bring it in, get it inspected, and have them release it - and those guys KNOW what headers look like...
If you have other cars, I've found that the best way to get a 'grey area' car passed is to bring your other cars in first. I have three that need to be smogged within a month of each other, and all three of them look/sound sketchy - but the first two are 100% CARB compliant. The third has some stuff that won't pass if caught. I bring the first two in, get to know the tech, and by the time I bring the third car in, he just connects the tailpipe sensor, plugs into the OBD port and I'm done in five minutes.