Chances are the car has overheated at some point. during such a overheating cycle, the computer is designed to dump fuel into the cylinders which cools the engine.
Even after cooling down and shutting off the engine, it will continue to run rich each time it is started and driven, until the computer is reset.
To reset the computer, unbolt the battery disconnect under the hood - leave it disconnected for a few minutes.
Re-connect, let all the guages cycle, you will see more lights than this years Christmas tree, then take it for a good long drive - 10-20 miles, running up thru the rev range in every gear. The computer will reset and that should be the end of the black soot all over the rear of the car