I agree that if the program for the Supercharger is programmed for the higher octane it would help.
I guess you could always put it in and see if it feels any different.
In the Porsche 993TT the factory computer will attempt to determine what the octane of the gas is and adjust the program accordingly. The effect you might say is "digital". You either have the advanced program or you don't. In a case such as that, the fuel makes a big difference. The effect does not feel linear you either have it or you don't.