Yes, I did try water on its own but it used to freeze around the throttle flap in cool weather and stick the throttle open, methanol fixed that. Pure water probably fine in the SR supercharger application and yes, methanol is corrosive to steel, and some other metals, but in two years use it was never a major problem, the nozzle was stainless, so it was ok. No ill effects in the motor at all.
I can see distribution being a problem in the manifold of the Roe supercharger, its base is quite flat and the ports are widely spread(due to the size of the motor, it isn't exactly a prissy little 1400cc 4 cyl !) It might be worth trying injecting into the supercharger inlet, dont think it could damage the rotors and it might evaporate nicely and distribute better, I'm sure Sean has his own ideas there.
BTW, don't think the methanol if used would act as a fuel, or at least not much, the quantities injected are relatively low in comparison with the main fuel(gas/petrol), but probably best to steer clear of methanol in this instance unless injecting before the throttle flaps which I think in this case wouldn't be a good place...