"Is Sean's system producing less boost than the other competitors?"
The Roe Supercharger System produces 5 psi so that the late model "Creampuff" Vipers with Hyper Cast Pistons will not self destruct. The hyper pistons are lighter than forged pistons and less weight means longer engine life.
The earlier Vipers had forged pistons that can take more of a boost without self destructing. Sean is working on an upgrade kit to boost his superchager system to the higher safe level that forged pistons can handle. Anything above 5 psi will require a bigger fuel pump. Air/fuel is very critical is a boosted engine - you do not want to run lean at full & even part boost.
Most other systems are for forged pistons only and the late model Vipers have to have new forged pistons put in.
Everything on the Roe Supercharger System is 1st class - I know from 1st hand experience. And just about everyone else has similar 1st class supercharger systems, too. But the Roe System can be installed where you live and you do not have to ship your Viper off to a tuner for however long it takes.
One of the things that sold me on the Roe System, other than Sean's reputation, is the horsepower and torque at lower RPMs - where I do almost all of my driving based on time at a given RPM - if you are peak RPM, then you are over the speed limit, so you let the RPMs drop back down to 1250-2500 to cruise in. That's where the design of the twin screw supercharger that Sean uses makes lots more power than the centrifugal systems. 6th gear with the stock 3.07 rear gear is very useable from 55 MPH on up - feels like 5th gear used to before the supercharger, and similarly, each gear feels like you are in the next lower gear.
" and which of the two systems you explained above is more reliable or has less moving parts?"
A single superchager will have less moving parts than a two superchagers set up, but I think any set up by a reputable tuner will be reliable. If you have more $, then you can buy more power. I'm not rich and the Roe Supercharger System with VEC2 was stretching my budget - I also added a lot of neccessary mods before even picked up my Viper so it would be ready for the Roe Supercharger. But, I am very happy with the Roe Superchager System and how it made my Viper so much easier to drive in everyday traffic. I still have a long way to go in getting to use the maximum power it has - I've only run it full throttle to 4,000 RPM in 4th gear (around 100 MPH) and it was accellerating like a rocket sled - I tried to smoothly go to full throttle in 3rd gear, but I'm over 100 MPH before the throttle is wide open - maybe I can do better once the weather gets better and the roads are cleaner.